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Merck
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T24007

Sigma-Aldrich

Tetramethylsilane

ACS reagent, NMR grade, ≥99.9%

동의어(들):

TMS

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About This Item

Linear Formula:
Si(CH3)4
CAS Number:
75-76-3
Molecular Weight:
88.22
Beilstein:
1696908
EC Number:
200-899-1
MDL number:
MFCD00008274
UNSPSC 코드:
12352103
PubChem Substance ID:
329826705
NACRES:
NA.22
bp:
26-28 °C (lit.)
vapor pressure:
11.66 psi ( 20 °C)

Grade

ACS reagent

Quality Level

200

vapor pressure

11.66 psi ( 20 °C)

분석

≥99.9%

양식

liquid

autoignition temp.

842 °F

expl. lim.

0.34-6.3 %

기술

NMR: suitable

증발 잔류물

≤0.05%

refractive index

n20/D 1.358 (lit.)

bp

26-28 °C (lit.)

mp

−99 °C (lit.)

density

0.648 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

C[Si](C)(C)C

InChI

1S/C4H12Si/c1-5(2,3)4/h1-4H3

InChI key

CZDYPVPMEAXLPK-UHFFFAOYSA-N

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관련 카테고리

애플리케이션

Tetramethylsilane can be used as:
  • A precursor to synthesize α-SiC by chemical vapor deposition.
  • A reactant to synthesize 1,3,5,7-tetramethyladamantane from adamantane in the presence of aluminum chloride and dichloromethane.
  • A solvent for the hydroaminomethylation of 1-octene with morpholine.
  • A methylating reagent for the conversion of germanium tetrachloride to tetramethylgermanium, trimethylgermanium chloride, dimethylgermanium dichloride or methylgermanium trichloride.

픽토그램

Flame
GHS02

신호어

Danger

유해 및 위험 성명서

H224

Hazard Classifications

Flam. Liq. 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

-16.6 °F - closed cup

Flash Point (°C)

-27 °C - closed cup

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
STBK8589
STBK5054
STBK3531
STBK1247
STBJ8367

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

COA 검색

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문서 라이브러리 방문

A novel approach to selecting thermomorphic multicomponent solvent systems (TMS) for hydroaminomethylation reactions
Behr A, et al.
Chemical Engineering and Processing, 69, 15-23 (2013)
Synthesis of alpha-SiC from tetramethylsilane by chemical vapor deposition at high temperature
Jeong S, et al.
Applied Physics Express, 7, 025501-025501 (2014)
Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
Organometallics, 1087-1089, 4-4 (1985)
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Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 65(3-4), 787-791 (2006-03-15)
The decomposition of trimethylsilane and tetramethylsilane has been investigated for the first time, using hot wire (catalytic) at various temperatures. Trimethylsilane is catalytic-dissociated in these species SiH(2), CH(3)SiH, CH(3), CH(2)Si. Time of flight mass spectroscopy signal of these species are
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