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939935

Sigma-Aldrich

Iron(II) chloride anhydrous

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≥99.99% trace metals basis

Synonym(s):

Iron(II) chloride, Ferrous chloride, Iron dichloride

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About This Item

Linear Formula:
FeCl2
CAS Number:
Molecular Weight:
126.75
MDL number:
form:
powder or crystals
solubility:
water: soluble

Quality Level

Assay

≥99.99% trace metals basis

form

powder or crystals

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impurities

≤100 ppm (trace metals analysis)

mp

677 °C (lit.)

solubility

water: soluble

density

3.16 g/mL at 25 °C (lit.)
3.16 g/mL at 25 °C

anion traces

chlorate, nitrate (as NO3-): ≤20 ppm
sulfate (SO42-): ≤20 ppm
≤50 ppm (oxygen)

cation traces

Al: ≤10 ppm
B: ≤10 ppm
Ba: ≤10 ppm
Ca: ≤10 ppm
Co: ≤10 ppm
Cr: ≤10 ppm
Cu: ≤10 ppm
K: ≤10 ppm
Mg: ≤10 ppm
Mn: ≤10 ppm
Na: ≤10 ppm
Ni: ≤10 ppm
Si: ≤10 ppm
Ti: ≤10 ppm
Zn: ≤10 ppm

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storage temp.

2-30°C

SMILES string

Cl[Fe]Cl

InChI

1S/2ClH.Fe/h2*1H;/q;;+2/p-2

InChI key

NMCUIPGRVMDVDB-UHFFFAOYSA-L

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General description

Iron(II) chloride, also known as Ferrous chloride, is a solid with paramagnetic properties and a high melting point. In general, the synthesis of ferrous chloride involves the addition of iron powder to a solution of hydrochloric acid in methanol. This reaction results in the formation of the methanol solvate of dichloride. Subsequently, by subjecting the solvate to vacuum and heating it at around 160 °C, the solvate transforms into anhydrous ferrous chloride (FeCl2).Iron(II) chloride exhibits solubility in tetrahydrofuran (THF), making it a crucial precursor material for the synthesis of organometallic compounds.
We are committed to bringing you Greener Alternative Products, which belongs to one of the four categories of greener alternatives. This product belongs to an Enabling category, and is used in the electrodeposition of iron-aluminum alloys for thermoelectric applications, enhancing energy conversion efficiency. This process, utilizing molten salt systems, contributes to sustainable energy technologies and supports the development of advanced materials for eco-friendly energy storage and conversion. Click here for more information.

Application

Thermoelectric materials have gained attention for their ability to directly convert temperature differences into electrical energy. High purity Iron(II) chloride, is used as a precursor for the synthesize of Heusler-type iron-based thermoelectric materials, Fe2XAl (X = V, Ti, etc.) for the use in thermoelectric conversion. For example: the binary Fe-Al thin films are synthesized using electrodeposition method in Iron(II) chloride containig quaternary molten salts which exhibited p- or n-type thermoelectric conversion, depending on their composition. In addition, our high purity Iron(II) chloride, anhydrous is also used as a source of Iron to produce supercapacitor material such as heteroatom -dopped porus carbon. In the synthesis process, Iron(II) chloride is used as catalyst and template to shape the structure of the electrode with large specific surface area, high specific capacitance along with excellent rate capability and cycle stability due to the combination of in situ molten salt templating and chemical blowing.

Features and Benefits

- >=99.99% trace metals basis (purity)
- Anhydrous
- Low water content
- Low Oxygen content
-Perfect use for molten salt reactors

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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