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Merck
모든 사진(1)

주요 문서

60109

Sigma-Aldrich

Potassium carbonate

puriss. p.a., ACS reagent, anhydrous, ≥99.0% (T)

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About This Item

Linear Formula:
K2CO3
CAS Number:
Molecular Weight:
138.21
Beilstein:
4267587
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NB.24

Grade

ACS reagent

Quality Level

grade

puriss. p.a.

분석

≥99.0% (T)

양식

powder or crystals

불순물

≤0.001% total nitrogen (N)
≤0.004% total sulfur (as SO4)

손실

≤1% loss on drying, 300 °C

pH

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

음이온 미량물

chloride (Cl-): ≤30 mg/kg
phosphate (PO43-): ≤10 mg/kg
silicate (as SiO2): ≤50 mg/kg

양이온 미량물

Ag: ≤5 mg/kg
Al: ≤5 mg/kg
As: ≤0.5 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Li: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤200 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Tl: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

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일반 설명

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene.

애플리케이션


  • Improved 2-pyridyl reductive homocoupling reaction using biorenewable solvent Cyrene (dihydrolevoglucosenone).: This study leverages potassium carbonate to enhance the homocoupling reaction of 2-pyridyl groups, showcasing its application in green chemistry for sustainable synthesis practices (Webb et al., 2023).

  • Synthesis, Characterization and Biological Evaluation of Magnolol and Honokiol Derivatives with 1,3,5-Triazine of Metformin Cyclization.: Potassium carbonate is used as a base in the synthesis of novel triazine derivatives, demonstrating its role in the development of biologically active compounds in pharmaceutical research (Ren et al., 2020).

  • Synthesis of (18) F-radiolabeled organophosphine fluorides for thiol-chemoselective peptide conjugation.: This article highlights the use of potassium carbonate in the preparation of radiolabeled compounds, essential for advancements in peptide conjugation and imaging techniques in molecular biology (Zhuang et al., 2020).

  • Molten-salt treatment of waste biomass for preparation of carbon with enhanced capacitive properties and electrocatalytic activity towards oxygen reduction.: Potassium carbonate is employed in molten-salt treatments to convert biomass into high-performance carbon materials, illustrating its importance in energy storage and environmental applications (Lu et al., 2016).

기타 정보

Reagent for the decomposition of silicates by fusioncitationcitation

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

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문서 라이브러리 방문

R. Bock
Aufschlussmethoden der anorg. & org. Chemie (1972)
Z. Sulcek et al.
Methods of Decomposition in Inorganic Analysis (1989)
Chelating N-heterocyclic carbene ligands in palladium-catalyzed Heck-type reactions.
Herrmann WA, et al.
Journal of Organometallic Chemistry, 557(1), 93-96 (1998)
Robert Möckel et al.
Organic letters, 17(7), 1644-1647 (2015-03-21)
The cobalt-catalyzed Diels-Alder reaction of trimethylsilyl-substituted alkynes with 1,3-dienes led to dihydroaromatic intermediates which were transformed into iodobenzene derivatives. For this transformation, the dihydroaromatic intermediates had to be oxidized and the trimethylsilyl-substituted arene had to undergo a silicon-iodine exchange reaction.
Synthesis, kinetic observations and characteristics of polyarylene ether sulphones prepared via a potassium carbonate DMAC process.
Viswanathan R, et al.
Polymer, 25(12), 1827-1836 (1984)

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