185302
Diisopropyl ether
ReagentPlus®, 99%, contains either BHT or hydroquinone as stabilizer
동의어(들):
Isopropyl ether
로그인조직 및 계약 가격 보기
모든 사진(1)
About This Item
Linear Formula:
(CH3)2CHOCH(CH3)2
CAS Number:
Molecular Weight:
102.17
Beilstein:
1731256
EC Number:
MDL number:
UNSPSC 코드:
12191502
PubChem Substance ID:
NACRES:
NA.07
bp:
68-69 °C (lit.)
vapor pressure:
120 mmHg ( 20 °C)
추천 제품
vapor density
3.5 (vs air)
Quality Level
vapor pressure
120 mmHg ( 20 °C)
제품 라인
ReagentPlus®
분석
99%
양식
liquid
autoignition temp.
827 °F
expl. lim.
1-21 %, 100 °F
dilution
(for general lab use)
refractive index
n20/D 1.367 (lit.)
bp
68-69 °C (lit.)
mp
−85 °C (lit.)
density
0.725 g/mL at 25 °C (lit.)
SMILES string
CC(C)OC(C)C
InChI
1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3
InChI key
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N
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일반 설명
Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent. Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed. Its efficacy as a fuel additive has been reported. When released in the atmosphere, it undergoes photodecomposition by reacting with OH radicals. Kinetics and mechanism of its reaction in atmosphere have been reported.
애플리케이션
Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.
법적 정보
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Flam. Liq. 2 - STOT SE 3
표적 기관
Central nervous system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point (°F)
-20.2 °F - closed cup
Flash Point (°C)
-29 °C - closed cup
이미 열람한 고객
Atmospheric chemistry of automotive fuel additives: diisopropyl ether.
Wallington TJ, et al.
Environmental Science & Technology, 27(1), 98-104 (1993)
Eagleson M.
Concise Encyclopedia Chemistry, 325-325 (1994)
Single stage synthesis of diisopropyl ether-an alternative octane enhancer for lead-free petrol.
Heese FP, et al.
Catalysis Today, 49(1), 327-335 (1999)
Novel (R)-oxynitrilase sources for the synthesis of (R)-cyanohydrins in diisopropyl ether.
Kiljunen E and Kanerva LT.
Tetrahedron Asymmetry, 8(8), 1225-1234 (1997)
A Azim et al.
Bioorganic & medicinal chemistry, 9(5), 1345-1348 (2001-05-30)
An efficient lipase catalysed synthesis of optically enriched alpha-halogenated amides with concomitant optical enrichment of the starting alpha-haloesters is described. Candida antarctica lipase (CAL) was found to be a better catalyst over porcine pancreatic lipase (PPL) and Candida cylindracea lipase
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