394874

1-(Trimethylsilyl)imidazole

LiChropur^™

• 동의어(들): TSIM, N-Trimethylsilylimidazole, TMSI
• 실험식(Hill 표기법): C₆H₁₂N₂Si
• CAS Number: 18156-74-6
• Molecular Weight: 140.26
• Beilstein: 606148
• EC Number: 242-040-3
• MDL number: MFCD00005280
• UNSPSC 코드: 41115716
• PubChem Substance ID: 329755874
• NACRES: NA.22

속성

• Grade: derivatization grade ((GC derivatization))
• Quality Level: 100
• 분석: ≥94.0%
• 품질: LiChropur^™
• 반응 적합성: reagent type: derivatization reagent; reaction type: Silylations
• 기술: gas chromatography (GC): suitable
• refractive index: n20/D 1.475 (lit.)
• bp: 93-94 °C/14 mmHg (lit.)
• density: 0.956 g/mL at 25 °C (lit.)
• SMILES string: C[Si](C)(C)n1ccnc1
• InChI: 1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
• InChI key: YKFRUJSEPGHZFJ-UHFFFAOYSA-N

설명

일반 설명

1-(Trimethylsilyl)imidazole (TMSIM) has high silyl donor ability. It does not react with amino groups and also does not help in formation of enol-ether on unprotected ketone groups. It is useful as a silylating agent for ecdysones, norepinephrine, dopamine, steroids, sugars, sugar phosphates and ketose isomers.

Powerful silylating agent, particularly for alcohols; Synthesis of acyl imidazolides

애플리케이션

1-(Trimethylsilyl) imidazole may be used for the synthesis an O-silylated derivative of a hexahomotriazacalix[3]arene. It may also be used for the silylation of Ti-MCM-41 catalyst, to study its effect on the olefin epoxidation with aqueous H₂O₂, 1-(Trimethylsilyl) imidazole was found to improve the hydrophobicity and the catalytic performance of Ti-MCM-41.

Learn more in the Product Information

기타 정보

Reagent for trimethylsilyl and trimethylsilyl ether.

법적 정보

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H302,H315,H319
• 예방조치 성명서: P210 - P233 - P240 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 42.8 °F - closed cup
• Flash Point (°C): 6 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter