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Merck
모든 사진(1)

주요 문서

T25305

Sigma-Aldrich

Tetraphenylarsonium(V) chloride hydrate

97%

동의어(들):

Phenylarsonium chloride, Tetraphenylarsenic chloride

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About This Item

Linear Formula:
(C6H5)4As(Cl) · xH2O
CAS Number:
Molecular Weight:
418.79 (anhydrous basis)
Beilstein:
3580063
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

97%

반응 적합성

core: arsenic
reagent type: catalyst

mp

258-260 °C (lit.)

SMILES string

O.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20As.ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;/h1-20H;1H;1H2/q+1;;/p-1

InChI key

NGDWSDTZKCSLRK-UHFFFAOYSA-M

애플리케이션

Cation exchange reagent. Used to prepare arsonium amide, oxime, and carbohydrate derivatives.

픽토그램

Skull and crossbonesEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

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문서 라이브러리 방문

E Bibi et al.
Proceedings of the National Academy of Sciences of the United States of America, 90(19), 9209-9213 (1993-10-01)
We describe functional expression of the mouse multidrug-resistance protein (P-glycoprotein; P-gp) in an Escherichia coli mutant defective in the outer membrane protease ompT. Heterologously expressed mdr1 appears as an unglycosylated species with an apparent molecular mass of 140 kDa in
Effect of phosphonium and arsonium salts on the differential-pulse polarograms of three permitted synthetic food colouring matters.
A G Fogg et al.
The Analyst, 112(9), 1319-1321 (1987-09-01)
K Yoshioka et al.
Experientia, 42(9), 1022-1023 (1986-09-15)
The effect of lipophilic cations such as triphenylmethylphosphonium, tetraphenylphosphonium and tetraphenylarsonium in addition to dibenzyldimethylammonium on thiamine transport in isolated rat hepatocytes was studied. Lipophilic cations at the concentration 10 microM almost completely inhibited thiamine uptake. Kinetic studies showed that
A M George et al.
Archives of biochemistry and biophysics, 333(1), 66-74 (1996-09-01)
In this preliminary study, we report the cloning of the human MDR1 cDNA into a prokaryotic expression vector and the consequent functional expression of heterologous P-glycoprotein in Escherichia coli. We demonstrate increased resistance to the P-glycoprotein substrates TPA+, TPP+, and
J A Podcasy et al.
Journal of chromatography, 315, 111-118 (1984-12-19)
The effect of the hetaerons tetraphenylarsonium chloride (Ph4AsCl) and tetraphenylarsonium perchlorate (Ph4AsClO4) on the retention of neutral and cationic metalloporphyrins on a reversed-phase column with an acetonitrile-tetrahydrofuran (85:15, v/v) mobile phase was investigated. The adsorption properties of the two hetaerons

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