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Merck
모든 사진(1)

주요 문서

939587

Sigma-Aldrich

Lithium nickel manganese cobalt oxide

new

lithium-niobate coated NMC622 cathode active material

동의어(들):

LiNbO3-coated NMC622, NMC622

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About This Item

실험식(Hill 표기법):
LiNi0.6Mn0.2Co0.2O2
CAS Number:
Molecular Weight:
96.93
UNSPSC 코드:
26111700

Grade

battery grade

Quality Level

설명

application(s): battery manufacturing

분석

99% trace metals basis

양식

powder

분자량

96.93 g/mol

구성

LiNi0.6Mn0.2Co0.2O2

density

4.8 g/cm3 ((lit.))

일반 설명

Lithium niobate coated NMC622 is a powdered form of lithium nickel manganese cobalt oxide with a stoichiometry of 6:2:2 Ni:Mn:Co and a typical particle size of 4-10 microns. The particles are coated in 5-10 nm amorphous lithium niobate, less than 1 wt.%.

애플리케이션

LiNbO3-coated NMC622 is a high-performance cathode active material specially designed for lithium-ion batteries (LIBs), particularly solid-state and high-voltage batteries. With a balance of 60% nickel for high capacity and 40% manganese and cobalt for structural stability, NMC622 surpasses NMC811 in terms of cycling lifetime and coulombic efficiencies and offers higher capacity than NMC532. The LiNbO3 coating plays a vital role in enhancing the stability of the cathode material by safeguarding the electrode and electrolyte from undesired reactions. Research suggests that this lithium-niobate coating mitigates reactions between the cathode material and electrolyte, reducing capacity fade over time and impeding the release of metal ions from the NMC cathode. Additionally, the LiNbO3 “insertion layer” improves rate capability by minimizing the space charge layer barrier at the electrolyte/cathode interface. This advancement translates to superior Li diffusion and reduced electrode polarization.

특징 및 장점

•NMC622: High capacity and long cycle lifetimes
•LiNbO3 coating: Enhanced protection for cathode and electrolyte, leading to improved coulombic efficiency
•LiNbO3 insertion layer: Boosts rate capability

픽토그램

Health hazardExclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Carc. 2 - Skin Sens. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

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