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Merck
모든 사진(3)

주요 문서

938734

Sigma-Aldrich

EPhos Pd G6 Br

greener alternative

동의어(들):

(EPhos)Pd(p-CF3C6H4)(Br)

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About This Item

실험식(Hill 표기법):
C43H59BrF3OPPd
Molecular Weight:
866.22
UNSPSC 코드:
12352100
NACRES:
NA.21

양식

powder

Quality Level

반응 적합성

core: palladium
reaction type: Cross Couplings
reagent type: catalyst

환경친화적 대안 제품 특성

Catalysis
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sustainability

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색상

faint yellow

작용기

phosphine

환경친화적 대안 카테고리

SMILES string

CC(C)OC1=CC=CC(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=C1[P]([Pd](Br)C3=CC=C(C(F)(F)F)C=C3)(C4CCCCC4)C5CCCCC5

InChI

InChI=1S/C36H55OP.C7H4F3.BrH.Pd/c1-24(2)28-22-32(25(3)4)35(33(23-28)26(5)6)31-20-15-21-34(37-27(7)8)36(31)38(29-16-11-9-12-17-29)30-18-13-10-14-19-30;8-7(9,10)6-4-2-1-3-5-6;;/h15,20-27,29-30H,9-14,16-19H2,1-8H3;2-5H;1H;

InChI key

BUVPEGXQNXKJOG-UHFFFAOYSA-N

관련 카테고리

일반 설명

(EPhos Pd G6 Br) is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

The Buchwald G6 precatalysts are oxidative addition complexes (OACs), which exhibit the same advantages as the previous generations of Buchwald precatalysts: quantitative generation of L–Pd(0), thermal stability, air stability, moisture stability, ease of handling, and high efficiency.

관련 제품

제품 번호
설명
가격

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

Lot/Batch Number

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문서

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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