908568

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆

≥95%

• 동의어(들): [5,5′-Bis(trifluoromethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate
• 실험식(Hill 표기법): C₃₆H₁₆F₂₂IrN₄P
• CAS Number: 1973375-72-2
• Molecular Weight: 1145.69
• MDL number: MFCD31707657
• UNSPSC 코드: 12352101
• NACRES: NA.22

속성

• 분석: ≥95%
• 양식: powder or crystals
• 반응 적합성: reaction type: Photocatalysis; reagent type: catalyst
• mp: >300 °C
• 광촉매 활성화: 460 nm
• SMILES string: [Ir+](c5c(c(cc(c5)F)F)c6ncc(cc6)C(F)(F)F)c3c(c(cc(c3)F)F)c4ncc(cc4)C(F)(F)F.FC(F)(F)c1cnc(cc1)c2ncc(cc2)C(F)(F)F.F[P-](F)(F)(F)(F)F
• InChI: 1S/C12H6F6N2.2C12H5F5N.F6P.Ir/c13-11(14,15)7-1-3-9(19-5-7)10-4-2-8(6-20-10)12(16,17)18;2*13-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-7(2,3,4,5)6;/h1-6H;2*1-2,4-6H;;/q;;;-1;+1
• InChI key: QEXYETWHTSSWGM-UHFFFAOYSA-N

설명

애플리케이션

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆ is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations including the alkylation of remote C-H bonds and alkene aminoarylation.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

기타 정보

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Arylsulfonylacetamides as bifunctional reagents for alkene aminoarylation

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable