900258

Isopropoxy(phenyl)silane

• 동의어(들): RubenSilane
• 실험식(Hill 표기법): C₉H₁₄OSi
• CAS Number: 910037-63-7
• Molecular Weight: 166.29
• MDL number: MFCD31707672
• UNSPSC 코드: 12352005
• NACRES: NA.22

속성

• 양식: liquid
• Quality Level: 100
• 반응 적합성: reagent type: reductant; reaction type: Reductions
• refractive index: n/D 1.4799
• density: 0.926 g/mL
• 저장 온도: 2-8°C
• SMILES string: [SiH2](OC(C)C)c1ccccc1
• InChI: 1S/C9H14OSi/c1-8(2)10-11-9-6-4-3-5-7-9/h3-8H,11H2,1-2H3
• InChI key: XYMAHMLQCLMTDN-UHFFFAOYSA-N

설명

일반 설명

Isopropoxy(phenyl)silane is used as a stoichiometric reductant that allows for a significant decrease in catalyst loading, lower reaction temperatures, a wide range of functional group tolerance, and more diverse solvents in metal-catalyzed Mukaiyama hydrofunctionalizations.

애플리케이션

Isopropoxy(phenyl)silane can be used as a hydride source for alkene hydrofunctionalization reactions in the presence of metal catalysts, particularly under aprotic, nonalcoholic conditions. This reagent is considered as one of the most efficient stoichiometric reductants than phenylsilane because of its ability to exclude alcohol solvent from a series of catalytic reactions. When utilized, it allows the researcher to significantly decrease catalyst loadings, lower reaction temperatures, and employ more diverse solvents in iron- and manganese-catalyzed Mukaiyama hydrofunctionalizations.
It can be used as a reagent in:

• The hydrogenation of olefins
• Branch-selective olefin cross-coupling reactions
• Markovnikov alkene hydration/amination reactions

안전성 정보

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3