700223

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%

• 동의어(들): Mn(dpm)₃, Shenvi Hydrogenation Catalyst, Mn(TMHD)₃, Tris(dipivaloylmethanato)manganese
• Linear Formula: Mn(C₁₁H₁₉O₂)₃
• CAS Number: 14324-99-3
• Molecular Weight: 604.74
• MDL number: MFCD00269825
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329762189
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 양식: crystals
• 반응 적합성: core: manganese; reagent type: catalyst
• mp: 160-170 °C
• SMILES string: CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
• InChI key: ORZPLLPBZHORSD-LWTKGLMZSA-K

설명

애플리케이션

Catalyst for:

• Intramolecular Diels-Alder reactions
• Single electron donor for excess electron transfer studies in DNA
• Enantioselective synthesis
• Borylation reactions
• Hydrohydrazination and hydroazidation
• Oxidative carbonylation of phenol

Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves