모든 사진(1)
About This Item
실험식(Hill 표기법):
C17H23NO5
CAS Number:
Molecular Weight:
321.37
Beilstein:
3624582
MDL number:
UNSPSC 코드:
12352209
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
≥98.0% (HPLC)
양식
powder
반응 적합성
reaction type: Boc solid-phase peptide synthesis
응용 분야
peptide synthesis
저장 온도
2-8°C
SMILES string
CC(C)(C)OC(=O)N[C@@H](Cc1ccc(OCC=C)cc1)C(O)=O
InChI
1S/C17H23NO5/c1-5-10-22-13-8-6-12(7-9-13)11-14(15(19)20)18-16(21)23-17(2,3)4/h5-9,14H,1,10-11H2,2-4H3,(H,18,21)(H,19,20)/t14-/m0/s1
InChI key
YIRRNENSHUFZBH-AWEZNQCLSA-N
애플리케이션
Due to gem-dimethyl substituent effect, Boc-Tyr(Allyl)-OH is found to be resistant to Claisen rearrangement in water.
기타 정보
Allyl group side-chain protected tyrosine; building block for unnatural amino acids by metathesis reaction
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
Aromatic Claisen Rearrangements of O?Prenylated Tyrosine and Model Prenyl Aryl Ethers: Computational Study of the Role of Water on Acceleration of Claisen Rearrangements.
Osuna S, et al.
European Journal of Organic Chemistry, 2013(14), 2823-2831 (2013)
Angewandte Chemie (International Edition in English), 114, 2964-2964 (2002)
A Loffet et al.
International journal of peptide and protein research, 42(4), 346-351 (1993-10-01)
Allyl and allyloxycarbonyl groups are used for the side-chain protection of amino acids. The protecting groups may be selectively cleaved using the reagent HSnBu3 under palladium catalysis. The preparation of Boc and Fmoc series of protected amino acids is described.
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