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Merck
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주요 문서

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731269

Sigma-Aldrich

2-Phenyl-2-propyl benzodithioate

99% (HPLC)

동의어(들):

2-Phenylpro-2-yl dithiobenzoate, Benzenecarbodithioic acid 1-methyl-1phenylethyl ester, Cumyl dithiobenzoate

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모든 사진(3)

About This Item

실험식(Hill 표기법):
C16H16S2
CAS Number:
201611-77-0
Molecular Weight:
272.43
MDL number:
MFCD18252676
UNSPSC 코드:
12352100
PubChem Substance ID:
329764638
NACRES:
NA.23

분석

99% (HPLC)

양식

solid

density

1.125 g/mL at 25 °C

SMILES string

CC(C)(SC(=S)c1ccccc1)c2ccccc2

InChI

1S/C16H16S2/c1-16(2,14-11-7-4-8-12-14)18-15(17)13-9-5-3-6-10-13/h3-12H,1-2H3

InChI key

KOBJYYDWSKDEGY-UHFFFAOYSA-N

관련 카테고리

일반 설명

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

애플리케이션

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylates/methacrylamides, and to a lesser extent acrylates/acrylamides and styrenes; Chain Transfer Agent (CTA)

픽토그램

Exclamation markEnvironment
GHS07,GHS09

신호어

Warning

유해 및 위험 성명서

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

219.9 °F

Flash Point (°C)

104.4 °C

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시험 성적서(COA)

Lot/Batch Number
MKBX4493V
MKBV1007V
BGBC3711V
BGBC3509V
MKBQ9853V

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COA 검색

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문서

Evaluation of RAFT Agents

A series of polymerization were carried out using RAFT agents and monomers yielding well-defined polymers with narrow molecular weight distributions. The process allows radical-initiated growing polymer chains to degeneratively transfer reactivity from one to another through the use of key functional groups (dithioesters, trithiocarbonates, xanthates and dithiocarbamates). RAFT agents help to minimize out-of-control growth and prevent unwanted termination events from occurring, effectively controlling polymer properties like molecular weight and polydispersity. RAFT agents are commercially available. RAFT does not use any cytotoxic heavy metal components (unlike ATRP).

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

모두 보기

프로토콜

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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