729353

Grubbs Catalyst^® M206

Umicore

• 동의어(들): Grubbs Catalyst^® M2a SIPR (C933), Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II)
• 실험식(Hill 표기법): C₅₂H₇₇Cl₂N₂PRu
• CAS Number: 373640-75-6
• Molecular Weight: 933.13
• MDL number: MFCD18643355
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329764471
• NACRES: NA.22

속성

• 양식: solid
• mp: 176-181 °C
• 저장 온도: 2-8°C
• SMILES string: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C
• InChI: 1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
• InChI key: VWYWCKUDPDENIJ-UHFFFAOYSA-L

설명

애플리케이션

• Bulky NHC ligand results in faster initiation than the Grubbs 2^nd Generation Catalyst.
• Has enabled lower catalyst loadings in some applications.

Grubbs Catalyst^® M2a SIPr is a second generation Grubb′s catalyst used to catalyze olefin metathesis which low catalyst loading. This is also used in synthesizing variety of highly active second generation fast-initiation Hoveyda type ruthenium catalysts.

기타 정보

Ruthenium-based catalysts for olefin metathesis

Grubbs Catalyst^® Technology for Olefin Metathesis by Sigma-Aldrich

법적 정보

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

안전성 정보

• 픽토그램: GHS02
• 신호어: Warning
• 유해 및 위험 성명서: H228
• 예방조치 성명서: P210
• Hazard Classifications: Flam. Sol. 2
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable