937355

ImPy-Trip-IPr*

≥95%

• Synonyme(s) : 2‐[2,6‐Bis(diphenylmethyl)‐4‐methylphenyl]‐5‐[2,4,6‐tris(propan‐2‐yl)phenyl]‐2H‐4Λ5‐imidazo[1,5‐a]pyridin‐4‐ylium chloride
• Formule empirique (notation de Hill) : C₅₅H₅₅ClN₂
• Numéro CAS: 2983007-59-4
• Poids moléculaire : 779.49
• Code UNSPSC : 12352142

Propriétés

• Niveau de qualité: 100
• Essai: ≥95%
• Forme: powder or crystals
• Capacité de réaction: reaction type: Cross Couplings
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Couleur: white to off-white
• Groupe fonctionnel: (Carbene)
• Autre catégorie plus écologique: Aligned
• Chaîne SMILES: CC(C=C1C(C2=CC=CC=C2)C3=CC=CC=C3)=CC(C(C4=CC=CC=C4)C5=CC=CC=C5)=C1N6C=[N+]7C(C=CC=C7C8=C(C(C)C)C=C(C(C)C)C=C8C(C)C)=C6.[Cl-]
• InChI: 1S/C55H55N2.ClH/c1-37(2)45-33-47(38(3)4)54(48(34-45)39(5)6)51-30-20-29-46-35-56(36-57(46)51)55-49(52(41-21-12-8-13-22-41)42-23-14-9-15-24-42)31-40(7)32-50(55)53(43-25-16-10-17-26-43)44-27-18-11-19-28-44;/h8-39,52-53H,1-7H3;1H/q+1;/p-1
• Clé InChI: RFDIMPRGVRMUES-UHFFFAOYSA-M

Description

Description générale

ImPy-Trip-IPr* is a member of a class of biaryl NHC ligands utilizing sterics to facilitate a well-defined L-shaped NHC. The unique shape allows for the development of cross-coupling reactions not possible with other NHC ligands, as well as an improvement in catalytic efficiency with many existing methods. Readily forms complexes with Pd, as well as Au, Cu, Rh, and other metals.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Active in the following reactions:

• Suzuki-Miyarua cross-coupling
• Buchwald-Hartwig amination
• Hydroxylation of aryl chlorides

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable