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Sigma-Aldrich

1-Chloro-3,3-dimethylbenziodoxole

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About This Item

Linear Formula:
C9H10ClIO
CAS Number:
69352-04-1
MDL number:
MFCD21648251
UNSPSC Code:
12352101
NACRES:
NA.22

form

solid

reaction suitability

reaction type: C-C Bond Formation

SMILES string

[I]1(OC(c2c1cccc2)(C)C)Cl

InChI

1S/C9H10ClIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3

InChI key

HEBYOYIIQNKPGQ-UHFFFAOYSA-N

Related Categories

Application

1-Chloro-3,3-dimethylbenziodoxole is a crystalline, air-stable, yellow chloroiodane compound which finds use as a starting material for production of other hypervalent iodine compounds. It can also be used as a mild chlorinating reagent. The compound shows good solubility in polar organic solvents, typically dichloromethane or ethyl acetate.

Automate your fluorination reactions with Synple Automated Synthesis Platform (SYNPLE-SC002)

Other Notes

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

Legal Information

Product of CF Plus Chemicals.

pictograms

Flame over circleExclamation mark
GHS03,GHS07

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Articles

Fluoroalkylation: Expansion of Togni Reagents

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

Fluoroalkylation: Expansion of Togni Reagents

The fluoroalkylation toolbox now includes Togni reagents, hypervalent iodine perfluoroalkylation reagents, fluoroalkyl bromides, silanes, carboxylates, and sulfonyl fluorides for late stage fluoroalkylation.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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