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910937

Sigma-Aldrich

di-phenylethylammonium lead(II) tetraiodide

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n = 1

Synonym(s):

(PEA)2PbI4, 2D perovskite, bis[(2-phenylethyl)ammonium] tetraiodoplumbate

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About This Item

Empirical Formula (Hill Notation):
C16H24N2PbI4
CAS Number:
131457-08-4
Molecular Weight:
959.19
MDL number:
MFCD32672282
UNSPSC Code:
12352101
NACRES:
NA.23

form

crystals

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Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

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Enabling,

SMILES string

[N+H3]CCc2ccccc2.[N+H3]CCc1ccccc1

InChI key

PSWSOAQTFFDDBM-UHFFFAOYSA-P

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for "Energy efficiency".

Application

Organic-inorganic hybrid perovskites based semiconducting materials exhibit excellent properties such as long charge carrier lifetime and diffusion length, and high photolumiscence quantum yield. These properties render the perovskite materials useful for applications in light emitting diodes (LEDs), lasers and photodetectors. The Bis[(2-phenylethyl)ammonium] tetraiomoplumbate is 2D-layered perovskite and finds applications in semiconductors, copper (II) probing, and in LEDs.

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

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Not applicable

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Chunqing Ma et al.
Chemical communications (Cambridge, England), 54(45), 5784-5787 (2018-05-22)
Stabilization of two-dimensional (2D) PEA2PbI4 (PEA is phenethylammonium) perovskite nanocrystals (PNCs) in water is achieved. By inhibiting the desorption process, the PNCs show exceptional stability for more than 2 months in PEA+ aqueous solutions. Stabilized PNCs are successfully applied for
Shuang Yang et al.
Angewandte Chemie (International ed. in English), 56(15), 4252-4255 (2017-03-16)
Two-dimensional (2D) organic-inorganic hybrid perovskite nanosheets (NSs) are attracting increasing research interest due to their unique properties and promising applications. Here, for the first time, we report the facile synthesis of single- and few-layer free-standing phenylethylammonium lead halide perovskite NSs
Ruddlesden?Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors.
Stoumpos C C, et al
Chemistry of Materials, 28, 2852-2867 (2016)
Giant Two-Photon Absorption and Its Saturation in 2D Organic?Inorganic Perovskite.
Liu W, et al.
Advanced Optical Materials, 5, 1601045-1601045 (2017)

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