761311

cataCXium^® A Pd G2

• Synonym(s): cataCXium A-Pd-G2, Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
• Empirical Formula (Hill Notation): C₃₆H₄₉ClNPPd
• CAS Number: 1375477-29-4
• Molecular Weight: 668.63
• MDL number: MFCD22200549
• UNSPSC Code: 12352300
• PubChem Substance ID: 329766924
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• feature: generation 2
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• mp: 220 °C (decomposition)
• functional group: amine; phosphine
• SMILES string: Nc1ccccc1-c2ccccc2[Pd]Cl.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
• InChI: 1S/C24H39P.C12H10N.ClH.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
• InChI key: CAVPLNLGXHYGIR-DVBMAMJVSA-M

Description

Application

cataCXium^® A Pd G2 is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols.[1]

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable