Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

571032

Sigma-Aldrich

Poly[9,9-bis-(2-ethylhexyl)-9H-fluorene-2,7-diyl]

light-emitting λem 409 nm (in chloroform)

Synonym(s):

Poly[9,9-di-(2′-ethylhexyl)fluorenyl-2,7-diyl]

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

CAS Number:
188201-16-3
MDL number:
MFCD03703236
UNSPSC Code:
12352103
NACRES:
NA.23

Quality Level

100

transition temp

Tg (DSC) 45 °C (onset)

solubility

THF: soluble
chloroform: soluble
toluene: soluble
xylene: soluble

λmax

374 nm

fluorescence

λex 362 nm; λem 409 nm in chloroform

SMILES string

C1(c2c(cccc2)c3c1cccc3)(CC(CCCC)CC)CC(CCCC)CC

InChI key

YJUVFJKHTNWDNU-UHFFFAOYSA-N

General description

Light-emitting, conjugated polymer exhibiting blue photo- and electroluminescence.
Poly[9,9-bis-(2-ethylhexyl)-9H-fluorene-2,7-diyl] (PFO) is a polyfluorene based conductive liquid crystalline material that can be used as a light emitting material. It forms a semiconducting layer to enhance the electroluminescence (EL) and performance of the photonic and optoelectronic devices.

Application

Organic Semiconductor Laser Materials
PFO forms a π-conjugating polymeric system that can produce blue EL devices which include organic light emitting diodes (OLEDs), optical fibers and molecular electronic devices.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCQ8794
MKCN0909
MKBL5793V
MKBD4261
11722EH

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

A Blue-Light-Emitting Polymer with a Rigid Backbone for Enhanced Color Stability
Park SH, et al.
Advances in Functional Materials, 17(16), 3063-3068 (2007)
Design and performance of active coupler for plastic optical fibres
Zubia J, et al.
Electronics Letters, 38(2), 65-67 (2002)
Polymer Light-emitting Diodes Based on End-capped Poly [9, 9-di-(2′ -ethylhexyl) fluorenyl-2, 7-diyl]
Zhang Q
Chin. J. Chem., 28(8), 1482-1486 (2010)
Blue polarized electroluminescence from a liquid crystalline polyfluorene
Grell M, et al.
Advanced Materials, 11(8), 671-675 (1999)
Amplified spontaneous emission spectra of poly (9, 9-dioctylfluorenyl-2, 7-diyl) under pulsed laser excitation
Ibnaouf KH
Synthetic Metals, 209, 534-543 (2015)

Articles

Organic Semiconductor Laser Materials

In this article, we demonstrate that bis-styrylbenzene derivatives show promising characteristics for very low lasing thresholds and discuss the design considerations for organic lasing molecules.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service