562289
3,5-Dichlorophenylmagnesium bromide solution
0.5 M in THF
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About This Item
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reaction suitability
reaction type: Grignard Reaction
Quality Level
concentration
0.5 M in THF
bp
65 °C
density
0.972 g/mL at 25 °C
functional group
chloro
storage temp.
2-8°C
SMILES string
Clc1cc(Cl)cc([Mg]Br)c1
InChI
1S/C6H3Cl2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1
InChI key
PWOVECVCCCTJFQ-UHFFFAOYSA-M
Related Categories
1 of 4
This Item | 562270 | 561029 | 562076 |
|---|---|---|---|
| concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 0.5 M in THF |
| density 0.972 g/mL at 25 °C | density 0.980 g/mL at 25 °C | density 0.971 g/mL at 25 °C | density 0.950 g/mL at 25 °C |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| bp 65 °C | bp - | bp 65 °C | bp 65 °C |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
Application
- In one of the key synthetic steps for the preparation of non-alternant polycyclic hydrocarbon named indeno-benzophenalene.[1]
- As a substrate in the synthesis of carboxylic esters by reacting with 2-methyl-4,6-pyrimidyl dicarbonates.[2]
- As a substrate in the synthesis of aryl ketones by reacting with acid chlorides using bis[2-(N,N-dimethylamino)ethyl] ether ligand.[3]
Legal Information
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-6.2 °F - closed cup
Flash Point(C)
-21.2 °C - closed cup
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