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Merck

260061

Sigma-Aldrich

2-Bromophenylacetic acid

99%

Synonym(s):

2-(2-Bromophenyl)acetic acid, 2-Bromobenzeneacetic acid, o-Bromophenylacetic acid

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$38.40
5 G
$159.00

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1 G
$38.40
5 G
$159.00

About This Item

Linear Formula:
BrC6H4CH2CO2H
CAS Number:
Molecular Weight:
215.04
Beilstein:
2250655
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

Assay

99%

form

solid

mp

104-106 °C (lit.)

functional group

bromo
carboxylic acid

SMILES string

OC(=O)Cc1ccccc1Br

InChI

1S/C8H7BrO2/c9-7-4-2-1-3-6(7)5-8(10)11/h1-4H,5H2,(H,10,11)

InChI key

DWXSYDKEWORWBT-UHFFFAOYSA-N

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1 of 4

This Item
H1637I2752532363
mp

95-97 °C (lit.)

mp

257 °C (dec.) (lit.)

mp

288 °C (dec.) (lit.)

mp

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

optical activity

[α]20/D −106°, c = 1 in ethanol

optical activity

-

optical activity

-

optical activity

[α]20/D −10°, neat

reaction suitability

reaction type: solution phase peptide synthesis

reaction suitability

-

reaction suitability

-

reaction suitability

-

application(s)

peptide synthesis

application(s)

peptide synthesis

application(s)

detection

application(s)

-

Application

2-Bromophenylacetic acid has been used:
  • as starting reagent in the synthesis of 8-methoxy-2-tetralone[1]
  • in the preparation of di-and tri-substituted 2-oxopiperazines on solid support[2]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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A peptoid based synthesis of di-and tri-substituted 2-oxopiperazines on solid support.
Goff DA.
Tetrahedron Letters, 39(12), 1473-1476 (1998)
Lee S, et al.
Synthetic Communications, 25(18), 2775-2780 (1995)

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