938718

Pd(COD)(DQ)

>95%

• Synonym(s): (1,5-Cyclooctadiene)(duroquinone) palladium(0), Pd(COD)(DQ) (COD=1,5-cyclooctadiene,DQ=duroquinone)
• Empirical Formula (Hill Notation): C₁₈H₂₄O₂Pd
• CAS Number: 86228-59-3
• Molecular Weight: 378.80
• UNSPSC Code: 12352100

Properties

• Quality Level: 100
• Assay: >95%
• form: powder or crystals
• reaction suitability: reagent type: catalyst; core: palladium; reaction type: Buchwald-Hartwig Amination; reagent type: catalyst; core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: catalyst; core: palladium; reaction type: Cross Couplings; reagent type: catalyst; core: palladium; reaction type: Heck Reaction; reagent type: catalyst; core: palladium; reaction type: Hiyama Coupling; reagent type: catalyst; core: palladium; reaction type: Miyaura Borylation Reaction
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• color: light brown to dark brown
• greener alternative category: Aligned
• storage temp.: 2-8°C
• SMILES string: O=C(C(C)=C(C1=O)C)C(C)=C1C.C[Pd](C)(C)C.C2C/C=C\CC/C=C\2
• InChI: InChI=1S/C10H12O2.C8H12.Pd/c1-5-6(2)10(12)8(4)7(3)9(5)11;1-2-4-6-8-7-5-3-1;/h1-4H3;1-2,7-8H,3-6H2;/b;2-1-,8-7-;
• InChI key: LDTNOVDKFHVJGF-GHDUESPLSA-N

Description

General description

Pd(COD)(DQ) is a rare example of a robust, air-stable, phosphine free 18 electron Pd(0) complex. The complex easily undergoes facile ligand exchange with a range of ancilliary ligands to give useful palladium compounds suitable for a range of catalytic transformations.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Zero-valent palladium species are active catalytic species in a range of useful catalytic reactions, including C-C coupling, C-N coupling, allylic substituion and alkene funcitonilizaiton reactions.

Features and Benefits

Pd(COD)(DQ) offers:

• High thermal and air stability.
• Benign ligands that do not interfere in catalytic reactions once ligand exchange has occurred.
• Good solution stability.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable