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Merck
모든 사진(5)

주요 문서

650560

Sigma-Aldrich

tert-Butyl methyl ether

HPLC Plus, for HPLC, GC, and residue analysis, 99.9%

동의어(들):

MTBE, Methyl tert-butyl ether

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About This Item

Linear Formula:
(CH3)3COCH3
CAS Number:
Molecular Weight:
88.15
Beilstein:
1730942
EC Number:
MDL number:
UNSPSC 코드:
12190000
PubChem Substance ID:
NACRES:
NA.07
bp:
55-56 °C (lit.)
vapor pressure:
4.05 psi

Grade

HPLC Plus

Quality Level

vapor density

3.1 (vs air)

vapor pressure

4.05 psi

분석

99.9%

양식

liquid

autoignition temp.

705 °F

expl. lim.

15.1 %

기술

HPLC: suitable
gas chromatography (GC): suitable

불순물

≤0.02% water
<1.0 ppb Fluorescence (quinine) at 365 nm

증발 잔류물

≤0.0001%

할로겐화 잔류물

≤10 ng/L (as heptachlor epoxide)

refractive index

n20/D 1.369 (lit.)

bp

55-56 °C (lit.)

mp

-110 °C

density

0.74 g/mL at 25 °C (lit.)

λ

H2O reference

UV 흡수

λ: 210 nm Amax: 1.0
λ: 225 nm Amax: 0.50
λ: 250 nm Amax: 0.10
λ: 300-400 nm Amax: 0.005

적합성

suitable for residue analysis

응용 분야

PFAS testing
food and beverages

SMILES string

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI key

BZLVMXJERCGZMT-UHFFFAOYSA-N

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일반 설명

tert-Butyl methyl ether is a gasoline additive. Its oxidative degradation by propane-oxidizing bacterial strains has been tested. Kinetics of its heat-assisted persulfate oxidation has been investigated at various pH, temperature, oxidant concentration and ionic strength levels. Its biodegradation followed a pseudo-first-order decay model and its pseudo-first-order rate constants were evaluated. MTBE can be synthesized by acid catalyzed reaction between methanol and isobutene. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method.

애플리케이션

Suitable for HPLC, spectrophotometry, environmental testing

포장

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

기타 정보

Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

추천 제품

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

법적 정보

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

FlameExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-18.4 °F - closed cup

Flash Point (°C)

-28 °C - closed cup


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

이미 열람한 고객

Lipid extraction by methyl-tert-butyl ether for high-throughput lipidomics.
Matyash V, et al.
Journal of Lipid Research, 49(5), 1137-1146 (2008)
New approach of catalyst-free biodiesel production from canola oil in supercritical tert-butyl methyl ether (MTBE).
Farobie O, et al.
Fuel: The Science and Technology of Fuel and Energy, 135, 172-181 (2014)
Role of tert-Butyl Methyl Ether (TBME) as an External Donor in Propene Polymerization with Dibutyl Phthalate (DBP)-Containing MgCl2-Supported Ti Catalysts Activated with Al(i-C4H9)3.
Ohnishi R and Konakazawa T.
Macromolecular Chemistry and Physics, 205(14), 1938-1947 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 154-154 (1994)
Carotenoid Extraction and Quantification from Capsicum annuum.
Richins RD, et al.
Bio-protocol, 4(19), e1256-e1256 (2014)

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