213349

Ammonium bromide

ACS reagent, ≥99.0%

• Linear Formula: NH₄Br
• CAS Number: 12124-97-9
• Molecular Weight: 97.94
• EC Number: 235-183-8
• MDL number: MFCD00011419
• UNSPSC 코드: 12352302
• eCl@ss: 38050407
• PubChem Substance ID: 329752145
• NACRES: NB.24

속성

• Grade: ACS reagent
• Quality Level: 200
• vapor pressure: 1 mmHg ( 198.3 °C)
• 분석: ≥99.0%
• 양식: powder or crystals
• 불순물: ≤0.005% insolubles
• 무기 잔류물: ≤0.01%
• pH: 4.5-6.0 (25 °C, 5%)
• mp: 452 °C (lit.)
• density: 2.43 g/mL at 25 °C (lit.)
• 음이온 미량물: bromate (BrO₃^-): ≤0.002%; chloride (Cl^-): ≤0.2%; iodide (I^-): ≤0.005%; sulfate (SO₄^2-): ≤0.005%
• 양이온 미량물: Ba: ≤0.002%; Fe: ≤5 ppm; heavy metals: ≤5 ppm (by ICP)
• SMILES string: N.Br[H]
• InChI: 1S/BrH.H3N/h1H;1H3
• InChI key: SWLVFNYSXGMGBS-UHFFFAOYSA-N

설명

일반 설명

Laser excited Raman spectral study reveals that 1?0 torsional transitions of the NH₄⁺ ion in phase III of NH₄Br were observed at 331cm^-1. Neutron diffraction studies have been conducted to evaluate the P-T phase diagram of NH₄Br and its deuterated form (ND₃Br).

애플리케이션

Ammonium bromide may be used in the preparation of organic ammonium tribromides. It may also be used as a reagent during the transformation of benzyl derivatives of halides, amines, alcohols, and aldehydes into respective nitriles via oxidation.

안전성 정보

• 픽토그램: GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H319,H336,H360FD,H362,H372
• 예방조치 성명서: P202 - P260 - P263 - P264 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Eye Irrit. 2 - Lact. - Repr. 1B - STOT RE 1 - STOT SE 3
• 표적 기관: Central nervous system, Nervous system
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 1
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable