176109

Mercury(II) acetate

ACS reagent, ≥98.0%

• 동의어(들): Mercuric acetate
• Linear Formula: (CH₃COO)₂Hg
• CAS Number: 1600-27-7
• Molecular Weight: 318.68
• Beilstein: 3563831
• EC Number: 216-491-1
• MDL number: MFCD00012165
• UNSPSC 코드: 12352103
• PubChem Substance ID: 329751548
• NACRES: NB.24

속성

• Grade: ACS reagent
• Quality Level: 200
• 분석: ≥98.0%
• 양식: powder
• 반응 적합성: reagent type: catalyst; core: mercury
• 불순물: ≤0.01% insolubles
• 산화 잔류물: ≤0.02%
• mp: 179-182 °C (lit.)
• 음이온 미량물: chloride (Cl^-): ≤0.005%; nitrate (NO₃^-): ≤0.005%; sulfate (SO₄^2-): ≤0.005%
• 양이온 미량물: Fe: ≤0.001%; Hg⁺: ≤0.4%; other heavy metals (as Pb): ≤0.002%
• SMILES string: CC(=O)O[Hg]OC(C)=O
• InChI: 1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
• InChI key: BRMYZIKAHFEUFJ-UHFFFAOYSA-L

설명

일반 설명

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.

애플리케이션

Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions. Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones). It may be used in the hydrothermal synthesis of [Hg₂(apca)₂]_n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg₂^{2 +} dumbbell.

안전성 정보

• 픽토그램: GHS06,GHS08,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H300 + H310 + H330,H373,H410
• 예방조치 성명서: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable