93335
Europium(III) tris[3-(heptafluoropropylhydroxymethylene)-d-camphorate]
puriss. p.a.
동의어(들):
Eu(hfc)3, Tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato]europium(III)
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C42H42EuF21O6
CAS Number:
Molecular Weight:
1193.71
EC Number:
MDL number:
UNSPSC 코드:
12352115
PubChem Substance ID:
NACRES:
NA.22
추천 제품
grade
puriss. p.a.
Quality Level
양식
powder
mp
~160 °C (lit.)
적합성
suitable for NMR (spectroscopy)
작용기
fluoro
ketone
저장 온도
2-8°C
SMILES string
CC1(C)C2CC[C@@]1(C)C(=O)C2=C(O[Eu](OC(=C3C4CC[C@@](C)(C3=O)C4(C)C)C(F)(F)C(F)(F)C(F)(F)F)OC(=C5C6CC[C@@](C)(C5=O)C6(C)C)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F
InChI
1S/3C14H15F7O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21;/h3*6,23H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7+;/t3*6-,11+;/m111./s1
InChI key
VGLKHVQPWGFXEG-PSMAIOHISA-K
애플리케이션
It may be used as the NMR shift reagent in the 1H NMR analysis to determine the following:
- Enantiomeric purities of the precursors of trisporic acids A, B and related products.
- Optical purity of racemic 6,7-dichloro-5-methoxy-2-methyl-2-phenyl-1 indanone.
- Epimeric purity of 4-methylsulfinylbutylglucosinolate.
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
기타 정보
Chiral shift reagent for the determination of enantiomer ratios by NMR ; Measurements in polar solvents; For use as a Lanthanide shift reagent
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
M. Calmes et al.
Tetrahedron, 43, 2285-2285 (1987)
Pirkle et al.
The Journal of Organic Chemistry, 44, 1025-1025 (1979)
L.M. Sweeting et al.
The Journal of Organic Chemistry, 52, 2273-2273 (1987)
Optical purity determination and 1H-NMR spectral simplification with lanthanide shift reagents-VIII. An indacrinone precursor, 6, 7-dichloro-5-methoxy-2-methyl-2-phenyl-1-indanone.
Hatzis A and Rothchild R.
Journal of Pharmaceutical and Biomedical Analysis, 4(4), 443-449 (1986)
Enantioselective synthesis of the white key intermediate for the synthesis of trisporic acids.
Bacigaluppo JA, et al.
Tetrahedron Asymmetry, 5(10), 1877-1880 (1994)
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