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Merck
모든 사진(1)

주요 문서

M4128

Sigma-Aldrich

Mercury(II) thiocyanate

96.5-103.5% (titration)

동의어(들):

Mercuric isothiocyanate, Mercuric sulfocyanide, Mercuric thiocyanate, Mercury di(thiocyanate), Thiocyanic acid, mercury(II) salt

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About This Item

Linear Formula:
Hg(SCN)2
CAS Number:
Molecular Weight:
316.75
Beilstein:
3561344
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

96.5-103.5% (titration)

반응 적합성

core: mercury
reagent type: catalyst

mp

165 °C (dec.) (lit.)

density

3.71 g/mL at 25 °C (lit.)

SMILES string

N#CS[Hg]SC#N

InChI

1S/2CHNS.Hg/c2*2-1-3;/h2*3H;/q;;+2/p-2

InChI key

GBZANUMDJPCQHY-UHFFFAOYSA-L

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일반 설명

Mercury(II) thiocyanate is the coordination complex of Hg2+ and the thiocyanate ion(SCN-). It is primary used as catalyst for the addition of thiocyanic acid (HSCN) across the triple bond of a variety of alkynes and as a precursor to synthesize other thiocyanate complexes. Within analytical chemistry, it is also used for the colorimetric determination of chloride ions in water.

애플리케이션

Mercury(II) thiocyanate can be employed as a reactant for the synthesis of:

  • Polymeric mercury(II) coordination complexes with various derivatives of 4,4′-bipyridine ligands via the branched tube method.
  • Manganese mercury thiocyanate (MMTC), an organometallic optical single-crystal.
  • Heterotrinuclear copper(II)–mercury(II)–copper(II)complexes possessing antibacterial and antifungal activities.

품질

Contains a small amount of mercurous thiocyanate insoluble in dilute acid.

면책조항

For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.

픽토그램

Skull and crossbonesHealth hazardEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

보충제 위험성

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point (°F)

248.0 °F - closed cup

Flash Point (°C)

120 °C - closed cup


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문서 라이브러리 방문

Mercury(II) Thiocyanate.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Mercury (II) acetate/thiocyanate coordination polymers with n-donor ligands, spectroscopic, thermal and structural studies.
Mahmoudi G , et al.
Inorgorganica Chimica Acta, 362(1), 217-225 (2009)
Mercury (II) coordination polymers generated from 1, 4-bis (2 or 3 or 4-pyridyl)-2, 3-diaza-1, 3-butadiene ligands.
Mahmoudi G, et al.
CrystEngComm, 9(8), 704-714 (2007)
Crystal growth and characterization of the organometallic nonlinear optical crystal: manganese mercury thiocyanate (MMTC).
Wang X Q, et al.
Materials Research Bulletin, 36(5-6), 879-887 (2001)
M A Koupparis et al.
Journal of pharmaceutical sciences, 75(8), 800-804 (1986-08-01)
An automated flow-injection determination of chloride salts of drugs, based on the colorimetric mercurothiocyanate determination of chloride counterion is described. The majority of these drugs can be determined, using chloride ion standards, with a coefficient of variation less than 1%

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