797693

2-Chloro-6-(trimethylsilyl)phenyl triflate

• 동의어(들): Garg 3-chlorobenzyne precursor
• 실험식(Hill 표기법): C₁₀H₁₂ClF₃O₃SSi
• CAS Number: 1449472-59-6
• Molecular Weight: 332.80
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768621
• NACRES: NA.22

속성

• 양식: liquid
• 작용기: chloro; fluoro; triflate
• 저장 온도: 2-8°C
• SMILES string: ClC1=C(OS(=O)(C(F)(F)F)=O)C([Si](C)(C)C)=CC=C1
• InChI: 1S/C10H12ClF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
• InChI key: QFWUIGWOSVHZMC-UHFFFAOYSA-N

설명

애플리케이션

Chlorosilyltriflate has been shown to be a useful precursor for the generation of a chlorobenzyne intermediate. The chlorobenzyne intermediate can be generated in the presence of Cesium or Potassium Fluoride and can be trapped with various dipolariphiles.

기타 정보

Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable