795569

Garg 4,5-indolyne precursor

95%

• 동의어(들): 4-(Trimethylsilyl)-1H-indol-5-yl trifluoromethanesulfonate
• 실험식(Hill 표기법): C₁₂H₁₄F₃NO₃SSi
• CAS Number: 1259448-37-7
• Molecular Weight: 337.39
• MDL number: MFCD25976536
• UNSPSC 코드: 12352100
• PubChem Substance ID: 329768491
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 95%
• 양식: solid
• mp: 43-48 °C
• 작용기: fluoro; triflate
• 저장 온도: 2-8°C
• SMILES string: O=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O
• InChI: 1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3
• InChI key: LLCJFYYASDIOJN-UHFFFAOYSA-N

설명

일반 설명

Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products).

애플리케이션

Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

기타 정보

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions

Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable