추천 제품
Quality Level
분석
95%
양식
solid
반응 적합성
reagent type: reductant
저장 온도
2-8°C
SMILES string
CC1=NC=CC=C1.B
InChI
1S/C6H7N.B/c1-6-4-2-3-5-7-6;/h2-5H,1H3;
InChI key
QHXLIQMGIGEHJP-UHFFFAOYSA-N
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일반 설명
2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.
애플리케이션
2-Methylpyridine borane complex solution (2-Picoline borane complex) was used as reducing agent for the labeling of oligosaccharides by reductive amination. It may be used in the following studies:
- Synthesis of alkoxyamine derivatives, via reduction of oxime ethers.
- Reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones.
- Synthesis of various trifluoromethylated amino compounds.
- An alternative reagent for reductive aminations.
Environmentally benign reducing agent
Reactant for:
Reductive amination
N-Benzyl-protection of amino acid derivatives by reductive alkylation
Reductive alkoxyamination
Reactant for:
Reductive amination
N-Benzyl-protection of amino acid derivatives by reductive alkylation
Reductive alkoxyamination
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
표적 기관
Respiratory system
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point (°F)
212.0 °F - closed cup
Flash Point (°C)
100 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex.
Kawase Y , et al.
Heterocycles, 78(2), 463-470 (2009)
Maaike M Appeldoorn et al.
Carbohydrate research, 381, 33-42 (2013-09-24)
In order to use corn fiber as a source for bioethanol production the enzymatic hydrolysis of the complex glucuronoarabinoxylans present has to be improved. Several oligosaccharides present in the supernatant of mild acid pretreated and enzymatically saccharified corn fiber that
Shigehisa Uchiyama et al.
Analytical chemistry, 81(1), 485-489 (2008-12-06)
A new method for the determination of carbonyls in air using 2,4-dinitrophenylhydrazine (DNPH) has been developed. The traditional method for the measurement of carbonyl compounds, using DNPH to form the corresponding 2,4-dinitrophenylhydrazone (DNPhydrazone) derivatives, is subject to analytical errors because
Sato, S. et al
Tetrahedron, 60, 7899-7899 (2004)
Trifluoroacetaldehyde: A useful industrial bulk material for the synthesis of trifluoromethylated amino compounds.
Mimura H, et al.
Journal of Fluorine Chemistry, 131(4), 477-486 (2010)
문서
2-picoline-borane (pic-BH3) is an excellent alternative reagent for reductive aminations.
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