추천 제품
Grade
anhydrous
vapor pressure
1 mmHg ( 190 °C)
분석
99.99% trace metals basis
양식
powder
반응 적합성
reagent type: catalyst
core: zirconium
불순물
<50 ppm hafnium
전이 온도
sublimation point 331 °C
density
2.8 g/mL at 25 °C (lit.)
응용 분야
battery manufacturing
SMILES string
Cl[Zr](Cl)(Cl)Cl
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
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일반 설명
Zirconium(IV) chloride (ZrCl4) is a Lewis acid catalyst, which has low toxicity. It is a moisture resistant material that is used as a catalyst in organic transformations.
애플리케이션
ZrCl4 can be used as a catalyst for a variety of organic syntheses, such as Friedel-Crafts reaction, condensation reaction and other reduction reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Met. Corr. 1 - Skin Corr. 1B
보충제 위험성
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
Stefania Fioravanti et al.
Organic & biomolecular chemistry, 10(41), 8207-8210 (2012-09-26)
ZrCl(4) was found to be an ideal catalyst to promote aza-Henry reactions between trifluoromethyl aldimines and some nitro alkanes giving new fluorinated β-nitro amines. The reaction is strongly influenced by the CF(3) group, the yield by the alkyl chain of
Abed Al Aziz Quntar et al.
The Journal of organic chemistry, 71(2), 730-733 (2006-01-18)
[reaction: see text] The reagent system Cp2ZrCl2/2EtMgBr/2AlCl3 converts 1-alkynylphosphonates into cyclopropylmethylphosphonates 3 in good isolated yields. Ethers, chlorides, and other cyclopropyl groups are compatible with the reaction conditions. Deuterium labeling is consistent with the formation of stable cyclopropylmethylbimetallic phosphonates by
Direct amide coupling of non-activated carboxylic acids and amines catalysed by zirconium(IV) chloride.
Helena Lundberg et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(13), 3822-3826 (2012-03-01)
관련 콘텐츠
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