모든 사진(3)
About This Item
Linear Formula:
LiBH4
CAS Number:
Molecular Weight:
21.78
EC Number:
MDL number:
UNSPSC 코드:
26111700
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
분석
≥95.0%
양식
solid
반응 적합성
reagent type: reductant
mp
275 °C (dec.)
density
0.666 g/mL at 25 °C (lit.)
SMILES string
[Li+].[BH4-]
InChI
1S/BH4.Li/h1H4;/q-1;+1
InChI key
UUKMSDRCXNLYOO-UHFFFAOYSA-N
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애플리케이션
Lithium borohydride is a general reducing agent commonly used to reduce aldehydes, ketones esters, lactones, and epoxides. It catalyzes hydroboration of alkenes. It is also used in the preparation of other borohydrides such as aluminum borohydride.
기타 정보
Review; Smooth reduction of esters; Reduction of acids and other functional groups with LiBH4/Me3SiCl
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
Mixed solvents containing methanol as useful reaction media for unique chemoselective reductions within lithium borohydride.
Soai, Kenso and Ookawa, Atsuhiro
The Journal of Organic Chemistry, 51(21), 4000-4005 (1986)
The Preparation of Other Borohydrides by Metathetical Reactions Utilizing the Alkali Metal Borohydrides1.
Schlesinger, HI et al.
Journal of the American Chemical Society, 75(1), 209-213 (1953)
LiBH 4-promoted hydroboration of alkenes with 1, 3, 2-benzodioxaborole.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(4), 205-206 (1991)
A. Giannis et al.
Angewandte Chemie (International Edition in English), 101, 220-220 (1989)
Lithium borohydride-catalyzed selective reduction of the carbonyl group of conjugated and unconjugated alkenones with borane in tetrahydrofuran.
Arase, Akira et al.
Journal of the Chemical Society. Chemical Communications, 51(7), 855-856 (1994)
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