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Merck
모든 사진(3)

주요 문서

60811

Sigma-Aldrich

Cobalt carbonyl

moistened with hexane (hexane 1-10%), ≥90% (Co)

동의어(들):

Cobalt tetracarbonyl dimer, Di-μ-carbonylhexacarbonyldicobal, Octacarbonyldicobalt, Dicobalt octacarbonyl

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About This Item

Linear Formula:
Co2(CO)8
CAS Number:
Molecular Weight:
341.95
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

≥90% (Co)

양식

solid

품질

moistened with hexane (hexane 1-10%)

반응 적합성

core: cobalt
reagent type: catalyst

저장 온도

2-8°C

SMILES string

[Co++].[Co++].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2

InChI key

MQIKJSYMMJWAMP-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

  • Cobalt carbonyl [Co2(CO)8] is commonly used as a catalyst in the hydroformylation (oxo reaction) of alkenes.
  • Along with pyridine, it can be used as a catalyst in the carboxylation of alkenes into corresponding acids and esters.
  • It is employed as a key precursor in the preparation of cobalt platinum (CoPt3), cobalt sulfide (Co3S4) and cobalt selenide (CoSe2) nanocrystals.
  • It is also used as a reagent in Pauson-Khand cyclizations and Nicholas reaction.

픽토그램

FlameSkull and crossbonesHealth hazard

신호어

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Repr. 2 - Self-heat. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation

표적 기관

Nervous system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point (°F)

-9.4 °F

Flash Point (°C)

-23 °C

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

In situ free-surfactant synthesis and ORR-electrochemistry of carbon-supported Co3S4 and CoSe2 nanoparticles.
Feng Y, et al.
Chemistry of Materials, 20(1), 26-28 (2007)
Dicobalt octacarbonyl.
Fischer S.
Synlett, 2002(09), 1558-1559 (2002)
Octacarbonyldicobalt.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-26 (2014)
M Varón et al.
Scientific reports, 3, 1234-1234 (2013-02-08)
Magnetostatic (dipolar) interactions between nanoparticles promise to open new ways to design nanocrystalline magnetic materials and devices if the collective magnetic properties can be controlled at the nanoparticle level. Magnetic dipolar interactions are sufficiently strong to sustain magnetic order at
A Lewis acid-mediated version of the Nicholas reaction: Synthesis of syn-alkylated products and cobalt-complexed cycloalkynes.
Schreiber SL, et al.
Journal of the American Chemical Society, 108(11), 3128-3130 (1986)

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