모든 사진(4)
About This Item
실험식(Hill 표기법):
Br2Pd
CAS Number:
Molecular Weight:
266.23
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
추천 제품
Quality Level
분석
99%
양식
powder
반응 적합성
reagent type: catalyst
core: palladium
density
5.173 g/mL at 25 °C (lit.)
SMILES string
Br[Pd]Br
InChI
1S/2BrH.Pd/h2*1H;/q;;+2/p-2
InChI key
INIOZDBICVTGEO-UHFFFAOYSA-L
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일반 설명
Palladium(II) bromide (PdBr2) is widely used as Pd(II) catalyst. PdBr2 can be prepared by reacting palladium metal with HNO3 and HBr. Electrosynthesis of PdBr2 from palladium metal and HBr has been reported.
애플리케이션
Palladium(II) bromide (PdBr2) has been used as a source of Pd(0) precatalyst in various coupling reactions. It was also employed as catalyst for the carbonylative Heck coupling reaction of aryl bromides and vinyl ethers.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
이미 열람한 고객
Palladium (II) Bromide.
Mahoney SJ, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Johannes Schranck et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4827-4831 (2012-03-17)
Three COming together: The first carbonylative Heck coupling reaction of aryl bromides and vinyl ethers leading to 1-aryl-3-alkoxy-2-propen-1-ones has been established (see scheme). Based on this coupling methodology, a novel one-pot synthesis of aryl-substituted pyrazoles was also realized.
문서
The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.
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