196436

(1R)-(−)-Fenchone

≥98%

• 동의어(들): (−)-1,3,3-Trimethyl-2-norbornanone, (−)-Fenchone, (1R)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
• 실험식(Hill 표기법): C₁₀H₁₆O
• CAS Number: 7787-20-4
• Molecular Weight: 152.23
• Beilstein: 2042710
• EC Number: 232-107-5
• MDL number: MFCD00151104
• UNSPSC 코드: 12352200
• PubChem Substance ID: 24851759
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: ≥98%
• 양식: liquid
• 광학 활성: [α]24/D −50.5°, neat
• refractive index: n20/D 1.461 (lit.)
• bp: 192-194 °C (lit.)
• mp: 5-6 °C (lit.)
• density: 0.948 g/mL at 25 °C (lit.)
• 작용기: ketone
• SMILES string: CC1(C)C2CCC(C)(C2)C1=O
• InChI: 1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
• InChI key: LHXDLQBQYFFVNW-OIBJUYFYSA-N

설명

일반 설명

(1R)-(-)-Fenchone is a bridged bicyclic ketone found in fennel oil and thuja oil.

애플리케이션

(1R)-(-)-Fenchone undergoes condensation with pyridinylalkylamines to form chiral iminopyridine ligands, which find applications in enantioselective copper-catalyzed Henry (nitro aldol) reaction. It may also be used in the preparation of enantiopure C(7)-anti-substituted fenchones as new chiral sources.

안전성 정보

• 픽토그램: GHS09
• 유해 및 위험 성명서: H411
• 예방조치 성명서: P273 - P391 - P501
• Hazard Classifications: Aquatic Chronic 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 2
• Flash Point (°F): 151.7 °F - closed cup
• Flash Point (°C): 66.5 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter