798371

Exo-Phenyl Kwon [2.2.1] Bicyclic Phosphine

95% (HPLC)

• 別名: (1S,4S,5R)-5-(phenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
• 実験式（ヒル表記法）: C₁₈H₂₀NO₂PS
• 分子量: 345.40
• MDL番号: MFCD28016350
• UNSPSCコード: 12352005
• PubChem Substance ID: 329768644
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 95% (HPLC)
• フォーム: powder
• 保管条件: under inert gas
• mp: 158-162 °C
• 官能基: phosphine; sulfonamide
• 保管温度: 2-8°C
• SMILES記法: CC1=CC=C(S(N2C[C@@]3([H])[P@](C4=CC=CC=C4)C[C@]2([H])C3)(=O)=O)C=C1
• InChI: 1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3
• InChI Key: BWXYDSDVFPJTFY-UHFFFAOYSA-N

詳細

アプリケーション

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

その他情報

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines

Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline

Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302
• 注意書き: P301 + P312 + P330
• 危険有害性の分類: Acute Tox. 4 Oral
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable