710733

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

• Synonym(s): 1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide
• Empirical Formula (Hill Notation): C₁₄H₂₂NO
• CAS Number: 61015-94-9
• Molecular Weight: 220.33
• MDL number: MFCD16621409
• UNSPSC Code: 12162002
• PubChem Substance ID: 329763005

Properties

• refractive index: n20/D 1.515
• density: 0.953 g/mL at 25 °C
• storage temp.: −20°C
• SMILES string: CC(C)C(N([O])C(C)(C)C)c1ccccc1
• InChI: 1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3
• InChI key: VGHCMXLEZFMZOZ-UHFFFAOYSA-N

Description

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator

Stable nitroxide radical useful in controlling living radical polymerizations

Safety Information

• Pictograms: GHS03,GHS06
• Signal Word: Danger
• Hazard Statements: H272,H301
• Precautionary Statements: P210 - P301 + P310 + P330
• Hazard Classifications: Acute Tox. 3 Oral - Ox. Liq. 3
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): 205.0 °F - closed cup
• Flash Point(C): 96.1 °C - closed cup