364282

Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)

98%

• Empirical Formula (Hill Notation): C₁₈H₂₄Cl₂N₂Pd₂
• CAS Number: 18987-59-2
• Molecular Weight: 552.14
• MDL number: MFCD29073987
• UNSPSC Code: 12161600
• PubChem Substance ID: 24862423
• NACRES: NA.22

Properties

• Assay: 98%
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 175 °C (dec.) (lit.)
• SMILES string: CN(C)Cc1ccccc1[Pd]Cl.CN(C)Cc2ccccc2[Pd]Cl
• InChI: 1S/2C9H12N.2ClH.2Pd/c2*1-10(2)8-9-6-4-3-5-7-9;;;;/h2*3-6H,8H2,1-2H3;2*1H;;/q;;;;2*+1/p-2
• InChI key: DSRDIGYUGAOPJI-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Oxidative allylic C-H silylation
• Transesterification reactions
• Suzuki-Miyaura cross-coupling reactions
• Stereocontrolled homologation of carbon chain boronic esters using Hoppe′s lithiated carbamates
• Oxidative carbonylation reactions
• Buchwald-Hartwig reactions
• Mizoroki-Heck reaction

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves