- Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.
Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.
Molecules (Basel, Switzerland) (2013-05-28)
Jana Doháňošová, Tibor Gracza
PMID23708231
ABSTRACT
The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.
MATERIALS
Product Number
Brand
Product Description
Palladium, foil, light tested, 100x100mm, thickness 0.047mm, as rolled, 99.95%
Palladium, foil, light tested, 100x100mm, thickness 0.075mm, as rolled, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, rod, 100mm, diameter 2.0mm, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%
Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, not light tested, 100x100mm, thickness 0.008mm, 99.95%
Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%
Palladium, microfoil, disks, 50mm, thinness 0.05μm, specific density 63.6μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, wire reel, 0.1m, diameter 0.25mm, hard, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.008mm, 99.95%
Palladium, foil, light tested, 25x25mm, thickness 0.075mm, as rolled, 99.95%
Palladium, wire reel, 1m, diameter 0.25mm, hard, 99.95%
Palladium, rod, 50mm, diameter 4.0mm, 99.95%
Palladium, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%
Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%
Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%
Palladium, foil, not light tested, 100x100mm, thickness 0.0125mm, 99.95%
Palladium, wire reel, 10m, diameter 0.025mm, as drawn, 99.9%
Palladium, microfoil, disks, 50mm, thinness 0.1μm, specific density 119.2μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, wire reel, 0.05m, diameter 1.0mm, hard, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.003mm, 99.95%
Palladium, wire reel, 0.1m, diameter 0.5mm, as drawn, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.0125mm, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.75%
Palladium, rod, 50mm, diameter 6.0mm, 99.95%
Palladium, wire reel, 0.2m, diameter 1.0mm, hard, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.05μm, specific density 63.6μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.95%