Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.

Molecules (Basel, Switzerland) (2013-05-28)

Jana Doháňošová, Tibor Gracza

ABSTRACT

The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.

MATERIALS

Product Number

Brand

Product Description

GF44874995

Palladium, foil, light tested, 100x100mm, thickness 0.047mm, as rolled, 99.95%

GF94632576

Palladium, foil, light tested, 100x100mm, thickness 0.075mm, as rolled, 99.95%

GF28406235

Palladium, microfoil, disks, 10mm, thinness 0.1μm, specific density 119.2μg/cm², permanent mylar 3.5μm support, 99.99%

GF81435146

Palladium, rod, 100mm, diameter 2.0mm, 99.95%

GF69074916

Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%

GF55245821

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF10106457

Palladium, foil, not light tested, 100x100mm, thickness 0.008mm, 99.95%

GF85707513

Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%

GF99402510

Palladium, microfoil, disks, 50mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF12546581

Palladium, wire reel, 0.1m, diameter 0.25mm, hard, 99.95%

GF99483351

Palladium, foil, not light tested, 50x50mm, thickness 0.008mm, 99.95%

GF62160409

Palladium, foil, light tested, 25x25mm, thickness 0.075mm, as rolled, 99.95%

GF40398352

Palladium, wire reel, 1m, diameter 0.25mm, hard, 99.95%

GF19845120

Palladium, rod, 50mm, diameter 4.0mm, 99.95%

GF02176332

Palladium, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.95%

GF03499016

Palladium, foil, not light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%

GF06424398

Palladium, tube, 120mm, outside diameter 6mm, inside diameter 5mm, wall thickness 0.5mm, as drawn, 99.95%

GF39094904

Palladium, tube, 50mm, outside diameter 1.0mm, inside diameter 0.8mm, wall thickness 0.1mm, as drawn, 99.95%

GF43081174

Palladium, foil, not light tested, 100x100mm, thickness 0.0125mm, 99.95%

GF52273852

Palladium, wire reel, 10m, diameter 0.025mm, as drawn, 99.9%

GF08208277

Palladium, microfoil, disks, 50mm, thinness 0.1μm, specific density 119.2μg/cm², permanent mylar 3.5μm support, 99.99%

GF61398197

Palladium, wire reel, 0.05m, diameter 1.0mm, hard, 99.95%

GF70629880

Palladium, foil, not light tested, 50x50mm, thickness 0.003mm, 99.95%

GF22660264

Palladium, wire reel, 0.1m, diameter 0.5mm, as drawn, 99.95%

GF59343688

Palladium, foil, not light tested, 50x50mm, thickness 0.0125mm, 99.95%

GF96367977

Palladium, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.75%

GF90054659

Palladium, rod, 50mm, diameter 6.0mm, 99.95%

GF92472688

Palladium, wire reel, 0.2m, diameter 1.0mm, hard, 99.95%

GF75251909

Palladium, microfoil, disks, 10mm, thinness 0.05μm, specific density 63.6μg/cm², permanent mylar 3.5μm support, 99.99%

GF37489540

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.95%