- Recoverable PEG-supported copper catalyst for highly stereocontrolled nitroaldol condensation.
Recoverable PEG-supported copper catalyst for highly stereocontrolled nitroaldol condensation.
Organic letters (2007-05-08)
Marco Bandini, Maurizio Benaglia, Riccardo Sinisi, Simona Tommasi, Achille Umani-Ronchi
PMID17480085
ABSTRACT
A new poly(ethylene glycol)-modified DAT2-Cu(OAc)2 complex smoothly catalyzes a base-free nitroaldol condensation in a highly enantioselective manner (ee up to 93%) also in reagent-grade solvent and in the presence of air. Effective recovery and recycling (up to five runs) of supported catalysts are documented.
MATERIALS
Product Number
Brand
Product Description
Pricing and availability is not currently available.
