- Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.
Asymmetric palladium-catalysed intramolecular Wacker-type cyclisations of unsaturated alcohols and amino alcohols.
Molecules (Basel, Switzerland) (2013-05-28)
Jana Doháňošová, Tibor Gracza
PMID23708231
ABSTRACT
The palladium (II)-catalysed reactions of alkenols and aminoalkenols such as oxycarbonylations or bicyclisations are powerful methods for the construction of oxygen and nitrogen-containing heterocyclic compounds. This review highlights recent progress in the development of the asymmetric palladium(II)-catalysed Wacker-type cyclisations of unsaturated polyols and aminoalcohols. The scope, limitations, and applications of these reactions are presented.
MATERIALS
Product Number
Brand
Product Description
Palladium, foil, light tested, 50x50mm, thickness 0.047mm, as rolled, 99.95%
Palladium, foil, not light tested, 150x150mm, thickness 0.0125mm, 99.95%
Palladium, foil, light tested, 25x25mm, thickness 0.006mm, 99.95%
Palladium, foil, not light tested, 25x25mm, thickness 0.005mm, 99.95%
Palladium, foil, light tested, 50x50mm, thickness 0.075mm, as rolled, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.003mm, 99.95%
Palladium, foil, not light tested, 150x150mm, thickness 0.025mm, as rolled, 99.95%
Palladium, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.95%
Palladium, microfoil, disks, 10mm, thinness 0.05μm, specific density 63.6μg/cm2, permanent mylar 3.5μm support, 99.99%
Palladium, foil, not light tested, 100x100mm, thickness 0.004mm, 99.95%
Palladium, foil, not light tested, 50x50mm, thickness 0.004mm, 99.95%
Palladium, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%
Palladium, rod, 25mm, diameter 4.0mm, 99.95%
Palladium, wire reel, 1m, diameter 0.05mm, as drawn, 99.9%
Palladium, wire reel, 0.2m, diameter 0.25mm, as drawn, 99.99+%
Palladium, wire reel, 2m, diameter 0.25mm, hard, 99.95%
Palladium, wire reel, 0.5m, diameter 0.5mm, as drawn, 99.95%
Palladium, wire reel, 1m, diameter 0.125mm, hard, 99.95%
Palladium, foil, 4mm disks, thickness 0.0125mm, 99.95%
Palladium, foil, 4mm disks, thickness 0.50mm, as rolled, 99.95%
Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.95%
Palladium, foil, 4mm disks, thickness 0.025mm, as rolled, 99.95%
Palladium, foil, 10mm disks, thickness 0.006mm, 99.95%
Palladium, foil, 100x100mm, thickness 0.1mm, as rolled, 99.95%
Palladium, foil, 10mm disks, thickness 0.25mm, as rolled, 99.95%
Palladium, foil, 25x25mm, thickness 0.50mm, as rolled, 99.99+%
Palladium, foil, 4mm disks, thickness 0.025mm, as rolled, 99.99+%
Palladium, foil, 15mm disks, thickness 0.047mm, as rolled, 99.95%