sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

GF88726168

Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%

GF49268526

Nickel, tube, 5mm, outside diameter 0.8mm, inside diameter 0.5mm, wall thickness 0.15mm, hard, 99.5%

GF81790690

Nickel, foil, 10mm disks, thickness 0.015mm, 99.9%

GF64774345

Nickel, foil, 10m coil, thickness 0.125mm, coil width 50mm, annealed, 99%

GF85861042

Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF05706389

Nickel, foil, 10mm disks, thickness 0.05mm, annealed, 99%

GF03085321

Nickel, foil, 10mm disks, thickness 0.005mm, as rolled, 99.9%

GF16803075

Nickel, foil, 2m coil, thickness 0.125mm, annealed, 99.98%

GF74649695

Nickel, foil, 2m coil, thickness 0.3mm, annealed, 99%

GF51323093

Nickel, tube, 500mm, outside diameter 3.6mm, inside diameter 3.5mm, wall thickness 0.05mm, hard, 99.5%

GF02127068

Nickel, foil, 10mm disks, thickness 0.0075mm, 99.9%

GF78640768

Nickel, foil, 2m coil, thickness 0.125mm, coil width 50mm, annealed, 99%

GF66058612

Nickel, foil, 10mm disks, thickness 0.025mm, 99.9%

GF35355315

Nickel, wire reel, 0.1m, diameter 0.75mm, as drawn, 99.99+%

GF03677665

Nickel, foil, 2m coil, thickness 0.15mm, annealed, 99%

GF45284081

Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%

GF25257573

Nickel, wire reel, 50m, diameter 0.25mm, annealed, 99%

GF07451906

Nickel, foil, 1m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF69120514

Nickel, foil, 1m coil, thickness 0.01mm, 99.95%

GF44855073

Nickel, foil, 15mm disks, thickness 0.25mm, as rolled, 100%

GF74554780

Nickel, wire reel, 50m, diameter 0.5mm, as drawn, 99%

GF41132708

Nickel, tube, 100mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF98441679

Nickel, foil, 1m coil, thickness 0.003mm, 99.95%

GF84917582

Nickel, tube, 200mm, outside diameter 0.65mm, inside diameter 0.384mm, wall thickness 0.133mm, as drawn, 99.5%